1-Chloromethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocuprate(II)
نویسنده
چکیده
In the crystal structure of the title compound, (C(7)H(15)ClN(2))[CuCl(4)], a weak inter-molecular N-H⋯Cl hydrogen bond is observed between the organic dication and the tetrahedral [CuCl(4)](2-) anion. The organic dication is distorted, as indicated by the N-C-C-N torsion angles, which range from 16.76 (4) to 19.54 (3)°.
منابع مشابه
1,2-Dimethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocuprate(II)
In the title compound, (C(8)H(18)N(2))[CuCl(4)], torsion angles on the ethyl-ene bridges of the 1,4-diazo-niabicyclo-[2.2.2]octane fragment are in the range 11.9 (5)-15.0 (5)° and the [CuCl(4)](2-) anion has a strongly distorted tetra-hedral geometry. The cation is connected to the anion via three-center N-H⋯Cl hydrogen bonds.
متن کامل1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocuprate(II)
In the crystal structure of the title compound, (C(8)H(15)N(3))[CuCl(4)], the cations and anions, in which the Cu(II) atom is tetra-hedrally coordinated, are linked via N-H⋯Cl hydrogen bonds into chains that are elongated in the c-axis direction.
متن کامل1-Chloromethyl-1,4-diazoniabicyclo[2.2.2]octane bis(hexafluorophosphate)
In the crystal structure of the title compound, C(7)H(15)ClN(2) (2+)·2PF(6) (-), the cations and anions are linked by inter-molecular N-H⋯F hydrogen bonds.
متن کامل1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridocadmate(II)
In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry. In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001]. C-H⋯Cl inter-actions also occur.
متن کامل1-Cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane tetrachloridomanganate(II)
In the crystal structure of the title compound, (C(8)H(15)N(3))[MnCl(4)], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetra-hedral geometry. Each [MnCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H⋯Cl hydrogen bonds, forming chains parallel to [001].
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